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Which of the following has the most negative electron affinity: Li,Be,N,O,F?


A) Li
B) Be
C) N
D) O
E) F

F) All of the above
G) A) and E)

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The energy difference between atomic cesium and its most stable ion,in the gaseous state,is referred to as ________.


A) atomic energy
B) electron affinity
C) entropy of vaporization
D) ionization energy
E) magnetic moment

F) A) and B)
G) A) and C)

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The transition elements refer to what group of elements?


A) s-block elements
B) d-block elements
C) actinides
D) lanthanides
E) p-block elements

F) B) and E)
G) A) and D)

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Which of the following pairs of elements are classified as metalloids?


A) aluminum and silicon
B) argon and neon
C) arsenic and germanium
D) bromine and sulfur
E) copper and silver

F) C) and D)
G) All of the above

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Choose the INCORRECT statement.


A) Within a given subshell,each orbital is usually occupied by a single electron before any orbital has two electrons.
B) When a metallic element unites with a nonmetallic element,electrons are lost by atoms of the metal and gained by atoms of the nonmetals.
C) The noble gas atoms complete the filling of the p orbitals.
D) The ionization energy of Ca+ is greater than that for Ca2+.
E) The radius of Ba2+ is smaller than the radius of Ba+.

F) A) and D)
G) A) and E)

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Which of the following reactions gives a positive value for the electron affinity?


A) S-(g) + e- → S2-(g)
B) O(g) + e- → O-(g)
C) S(g) + e- → S-(g)
D) Br(g) + e- → Br-(g)

E) A) and D)
F) None of the above

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Can alkali metal atoms form negative ions in the gaseous state? Explain.


A) No,an electron cannot be added.
B) No,only a liquid can be ionized.
C) Yes,an electron can be added to a Li half-filled 2s orbital.
D) Yes,an electron can be removed from a Li half-filled 2s orbital.
E) No,the 2s orbital is completely filled.

F) A) and B)
G) B) and D)

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Which 1+ ion is isoelectronic with S2-?

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Which of the following could never be isoelectronic species?


A) anions of two different elements
B) cations of two different elements
C) an anion and a cation
D) an anion and an atom
E) atoms of two different elements

F) None of the above
G) B) and D)

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List in order of increasing ionization potential: O,Mg,Rb,S,Si.


A) Si < O < Mg < Rb < S
B) Si < S < Rb < Mg < O
C) Mg < O < Rb < S < Si
D) Rb < Mg < Si < S < O
E) S < Si < Mg < O < Rb

F) A) and D)
G) C) and E)

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Of the following,which atom has the largest atomic radius?


A) Rb
B) I
C) Cs
D) At

E) None of the above
F) A) and C)

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Polarizability decreases with the size of the atom.

A) True
B) False

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List in order of increasing atomic size: F,Na,K,Mg,Ne.


A) K < Mg < Ne < Na < F
B) Ne < Mg < K < Na < F
C) Ne < F < Mg < Na < K
D) Mg < F < Ne < Na < K
E) K < Na < Mg < F < Ne

F) B) and E)
G) A) and E)

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Which of the following has the smallest value of the first ionization energy: Ar,Cs,N,Cu,Rb?


A) Ar
B) Cs
C) N
D) Cu
E) Rb

F) A) and E)
G) C) and E)

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The ion represented as The ion represented as  Ti<sup>4+</sup> has: A) 22 electrons B) 48 neutrons C) 26 protons D) 4 3d electrons E) 0 4s electronsTi4+ has:


A) 22 electrons
B) 48 neutrons
C) 26 protons
D) 4 3d electrons
E) 0 4s electrons

F) A) and D)
G) B) and C)

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List in order of increasing number of unpaired electrons: N,Na,Si,Cr,Ar.


A) Cr < Si < Na < N < Ar
B) Ar < Cr < N < Na < Si
C) Ar < Cr < Si < Na < N
D) N < Na < Cr < Si < Ar
E) Ar < Na < Si < N < Cr

F) B) and C)
G) A) and B)

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Which of the following species will have the highest ionization energy?


A) K+
B) Ar
C) Cl-
D) S2-

E) None of the above
F) All of the above

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What is the general valence electronic configuration (where n = principal quantum number) that best describes the halogens as a group?


A) ns1np6
B) ns2np4
C) ns2np5
D) ns2np6
E) ns2np3

F) A) and B)
G) C) and D)

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Which ionization process requires the most energy?


A) O(g) → O+(g) + e-
B) O+(g) → O2+(g) + e-
C) F(g) → F+(g) + e-
D) F+(g) → F2+(g) + e-

E) B) and C)
F) A) and D)

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The first ionization energy for rubidium is +403.0 kJ/mol.How much energy would be required to convert 17.1 g of gaseous rubidium to its gaseous +1 monatomic ion at constant temperature?


A) 185 kJ
B) 80.6 kJ
C) 68.9 kJ
D) 40.4 kJ
E) 34.5 kJ

F) C) and D)
G) A) and E)

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